Finite Volume Kolmogorov-Johnson-Mehl-Avrami Theory

Finite Volume Kolmogorov-Johnson-Mehl-Avrami Theory

Kolmogorov-Johnson-Mehl-Avrami (KJMA) theory of phase conversion is studied in finite volumes. For the conversion time one finds the relationship $tau_{rm con}/tau_{rm nu} =1+f_d(q)$. Here $d$ is the space dimension, $tau_{rm nu}$ the nucleation time in the volume $V$, and $f_d(q)$ a scaling function. Its dimensionless argument is $q$ reduces the original dependence on three variables (nucleation time, expansion velocity, Volume) to just one variable; $f_d(q)$ is calculated for d = 1, 2 and 3. The often considered limits of phase conversion via either a nucleation or a spinodal process are found to be volume-size dependent concepts, governed by simple power laws for $f_d(q)$. In the infinite volume limit the nucleation region disappears (i.e., the spinodal endpoints collapse to the critical point). Illustrations are given for Potts models.

Dept of Physics, Florida State University

The event is finished.

Date

8 June 2009
Expired!

Time

15h30 – 0h00

Location

Salle Claude Itzykson, Bât. 774
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