Are defect models consistent with the entropy and specific heat of glass formers?
Biroli G. (CEA, DSM, SPhT (Service de Physique Théorique), F-91191 Gif-sur-Yvette, FRANCE) Bouchaud J.-P. (CEA, IRAMIS, SPEC (Service de Physique de lEtat Condensé), F-91191 Gif-sur-Yvette, FRANCE) Tarjus G. (Laboratoire de Physique Théorique des Liquides (LPTL), CNRS, Université Pierre et Marie Curie, 4 Place Jussieu, F-75252 Paris Cedex, FRANCE)
Abstract: We show that point-like defect model of glasses cannot explain
thermodynamic properties of glass-formers, as for example the excess
specific heat close to the glass transition, contrary to the claim of
J.P. Garrahan, D. Chandler [Proc. Natl. Acad. Sci. {\bf 100}, 9710
(2003)]. More general models and approaches in terms of extended
defects are also discussed.